Styrene butadiene rubber (SBR), also known as polystyrene butadiene copolymer, is an important material in rubber industry. Its chemical structure is formed by copolymerization of styrene and butadiene monomer, usually the content of styrene is about 30%, which gives SBR unique physical and mechanical properties.
Styrene-butadiene rubber (SBR) is a white loose columnar solid with unsaturation, and its unsaturation is lower than that of natural rubber. It is not completely soluble in gasoline, benzene and chloroform, but it has good resistance to polar solvents such as acetone. In addition, styrene-butadiene rubber also has good wear resistance, heat resistance, aging resistance and vulcanization speed, which are even better than natural rubber in some aspects, and are even better in some aspects, such as wear resistance, heat resistance, aging resistance and vulcanization speed. Styrene-butadiene rubber products are widely used in the production of tires, tapes, hoses, wires and cables, medical appliances and various rubber products, and are one of the largest general synthetic rubber varieties, and also one of the earliest rubber varieties to realize industrial production.
key property
1. Unsaturation: providing structural basis for vulcanization and modification of styrene-butadiene rubber. The unsaturated degree of SBR is lower than that of natural rubber, and its vulcanization speed is slower, but its vulcanization flatness is good, its vulcanization reversion resistance is better, its processability is excellent, and its aging resistance is better than that of natural rubber.
2. Wear resistance: The wear resistance of styrene-butadiene rubber is better than that of cis-1,4-polybutadiene rubber, and it is suitable for tire top rubber.
3. Flexibility: Styrene-butadiene rubber is mainly composed of trans butadiene and styrene, which has large steric hindrance, poor molecular flexibility and poor cold resistance.
4. Non-polar: SBR has poor solubility resistance, especially non-polar solvents, such as gasoline and paraffin oil, but it has good resistance to polar solvents.
application area
Styrene-butadiene rubber is mainly divided into emulsion polymerized styrene-butadiene rubber (ESBR) and solution polymerized styrene-butadiene rubber (SSBR). Emulsion polymerized styrene-butadiene rubber is the highest yield styrene-butadiene rubber type at present, and its production technology is relatively mature and its cost is low. Solution polymerized styrene-butadiene rubber is gradually developed in recent years, which has the characteristics of high molecular weight, narrow molecular weight distribution and excellent wet skid resistance.
Styrene-butadiene rubber is widely used in many fields because of its excellent performance. In the tire industry, it is one of the main materials for manufacturing tire tread, sidewall and other parts. In addition, SBR is also used to manufacture conveyor belts, hoses, adhesives, sponge rubber, impregnated fibers and fabrics. In the aspect of high performance modification, SBR can be compounded or modified with other materials to improve its high temperature resistance, low temperature resistance or tear resistance.
As an important synthetic rubber, styrene-butadiene rubber plays an important role in modern industry with its excellent performance and wide application fields. With the continuous progress of science and technology and the continuous improvement of environmental protection requirements, the production and application of styrene-butadiene rubber will continue to develop, bringing more convenience and innovation to mankind.
Characteristics and uses of styrene-butadiene rubber
Styrene-butadiene rubber (SBR), also known as polystyrene-butadiene copolymer, is an important synthetic rubber. It is synthesized by copolymerization of butadiene and styrene, in which the content of styrene is usually around 30%. This unique chemical structure endows SBR with a series of unique physical and chemical properties, which makes it widely used in many fields.
Characteristics of styrene-butadiene rubber
1. Unsaturation : SBR has a certain degree of unsaturation, which provides a structural basis for its vulcanization and modification. Although its unsaturation is lower than that of natural rubber, its vulcanization speed is slow, its vulcanization flatness is good, and it has good resistance to vulcanization reversion. These characteristics make styrene-butadiene rubber show excellent properties during processing, and its aging resistance is also better than that of natural rubber.
2. Wear resistance : Styrene-butadiene rubber (SBR) has better wear resistance, which is second only to butadiene rubber (BR), so it is often used as the upper rubber material of tires.
3. Flexibility and cold resistance : Styrene-butadiene rubber is mainly composed of trans-butadiene and styrene, which has large steric hindrance, resulting in poor molecular flexibility and relatively low cold resistance. However, the flexibility and cold resistance can be improved to some extent by adjusting the content and chain structure of butadiene.
4. Non-polar : SBR has poor solubility resistance, especially non-polar solvents, such as gasoline and paraffin oil. But it has good resistance to polar solvents, such as acetone. This feature needs special attention during use.
5. Environmental protection : With the enhancement of environmental awareness, the development of environmentally friendly styrene-butadiene rubber has also made remarkable progress. Styrene-butadiene rubber (SBR) products that meet the requirements of environmental protection can be produced by using environmental protection additives and environmental protection filling oil.
The use of styrene-butadiene rubber
1. Tire manufacturing : Styrene-butadiene rubber is an important material in tire manufacturing, especially suitable for tire tread, sidewall and other parts. Its excellent wear resistance, aging resistance and vulcanization performance make the tire have longer service life and better driving performance.
2. Conveyor belts and hoses : Styrene-butadiene rubber is also widely used to manufacture rubber products such as conveyor belts and hoses. These products need to bear large tensile and compressive stresses, and the high strength and wear resistance of styrene-butadiene rubber make it an ideal choice.
3. Adhesives and sponge rubber : Styrene-butadiene rubber can also be used as raw materials for adhesives and sponge rubber. Its good adhesion and foaming properties make these products widely used in many fields.
4. Impregnating fibers and fabrics : Styrene-butadiene rubber can also be used to impregnate fibers and fabrics to improve their waterproof, oil and acid and alkali resistance. This application makes SBR have a certain market in the field of textile processing.
To sum up, with its unique chemical structure and excellent physical properties, styrene-butadiene rubber has a wide application prospect in many fields, such as tire manufacturing, conveyor belts and hoses, adhesives and sponge rubber, and impregnated fibers and fabrics. With the continuous progress of technology and the improvement of environmental protection requirements, the performance and application scope of styrene-butadiene rubber will continue to expand and improve.